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Recent Advances in Transition Metal-Free Halogenation of C(sp2)-H Bonds

[ Vol. 25 , Issue. 10 ]

Author(s):

Tian Luo, Shanghui Tian, Jie-Ping Wan* and Yunyun Liu*   Pages 1180 - 1193 ( 14 )

Abstract:


C-X (X = halogen) bonds are indispensable functional groups in organic synthesis by mediating a massive number of important organic reactions. While a variety of different catalytic strategies are available for generating C-X bonds, those methods enabling the C-X bond formation under transition metal-free conditions via the C-H bond functionalization are particularly interesting because of the inherent atom economy and environmental friendliness associated with such methods. Herein, the advancements in the transition metal-free halogenation of C(sp2)-H bond are reviewed.

Keywords:

C(sp2)-H bond, halogenation, transition metal-free, carbon arene, hereroaryl, non-aromatics.

Affiliation:

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022

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