Submit Manuscript  

Article Details


CO Surrogates: A Green Alternative in Palladium-Catalyzed CO Gas Free Carbonylation Reactions

[ Vol. 24 , Issue. 22 ]

Author(s):

Mayur V. Khedkar*, Shoeb R. Khan*, Trimurti L. Lambat*, Ratiram G. Chaudhary and Ahmed A. Abdala*   Pages 2588 - 2600 ( 13 )

Abstract:


Carbonylation reactions with carbon monoxide (CO) provide efficient and attractive routes for the synthesis of bulk and fine chemicals. However, the practice of using a large excess of an inflammable, lethal and greenhouse CO gas is always a concern in this chemistry. The development of CO surrogates has gained substantial interest and become a green alternative to gaseous CO. Many of the recent studies have focused on the development of other benign and safe reagents to work as a CO source in carbonylation reactions, and the assortment of feasible CO surrogates for specific reaction can be accomplished by the literature data. This review describes the recent developments in palladium-catalyzed carbonyl insertions without the direct use of gaseous CO.

Keywords:

Palladium, heterogeneous and homogeneous catalysis, coupling reaction, CO surrogates, carbonylation, CO gas free, green synthesis.

Affiliation:

Department of Chemistry, Hislop College, Nagpur 440001, Maharashtra, Department of Chemistry, Hislop College, Nagpur 440001, Maharashtra, Department of Chemistry, Manoharbhai Patel College of Arts, Commerce & Science, Deori, Gondia 441901, Maharashtra, Post Graduate Department of Chemistry, S. K. Porwal College of Arts, Commerce & Science, Kamptee-441001, Maharashtra, Chemical Engineering Program, Texas A & M University at Qatar, P.O.B. 23784, Doha

Graphical Abstract:



Read Full-Text article