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Amidoselenation of Alkenes Yielding the β-Amido-selenides through a Radical Pathway

[ Vol. 22 , Issue. 6 ]

Author(s):

Feng Zhao, Ting Sun, Zhenhua Liu, Kai Sun, Chong Zhang and Xin Wang*   Pages 613 - 618 ( 6 )

Abstract:


An efficient protocol for the intermolecular amidoselenation of alkenes with diphenyl diselenides and acetonitrile has been developed that affords a series of β-amidoselenides in high yields under mild conditions. The preliminary experimental results support the involvement of active benzyl radical species, and a radical pathway was therefore proposed for the reaction.

Keywords:

Alkenes, amidoselenation, radical, difunctionalization, β-amido-selenides, transformation.

Affiliation:

College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000

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