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Enynal/Enynone: A Safe and Practical Carbenoid Precursor

[ Vol. 20 , Issue. 1 ]

Author(s):

Jun Ma, Li Zhang and Shifa Zhu   Pages 102 - 118 ( 17 )

Abstract:


Recently, non-diazo carbene precursors have attracted more and more interest because of the apparent safety reason. As one of the most reliable and useful non-diazo carbenoid precursors, enynal/enynone can give rise to furyl- or pyrylium-carbene, which has be applied in a wide range of carbene-transfer reactions, such as cyclopropanation, C-H and X-H insertion, 1,3-dipolar cycloaddition and ylide formation reaction.

Keywords:

Carbene, enynal, enynone, cyclopropanation, C-H insertion, X-H insertion.

Affiliation:

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, P. R. China.

Graphical Abstract:



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